Chitosan/Poly(Amide-Imide) Blend Films: Studies on Thermal and Mechanical Stability, Morphology and Biodegradability

Authors

  • Ali Amoozadeh Department of Chemistry, Semnan University, Semnan, I.R. IRAN
  • Elaheh Kowsari Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
  • Mahdiyeh Ghasemi Department of Chemistry, Semnan University, Semnan, I.R. IRAN
Abstract:

A diacid monomer was synthesized by the condensation of L-tryptophan amino acid and pyromellitic dianhydride (PMDA). The diacid was utilized for the synthesis of three types of poly(amide-imide)s (PAIs) using three different kinds of diamines. The synthesized monomer and PAIs were characterized using FT-IR, 1H-NMR and 13C-NMR spectroscopies and the PAIs were also used for the fabrication of chitosan (CS)/PAI blend films. XRD patterns of the PAIs, CS and CS/PAI blend films were also studied. Thermal stability of PAIs, CS and CS/PAI samples were studied using thermogravimetric analysis (TGA). The blend samples showed a higher thermal stability compared to the CS film, especially at higher temperatures. Morphology of the CS and blend CS/PAI films were studied before and after the biodegradation by SEM. The mechanical stability studies showed that blend CS/PAI films had a proper mechanical strength and their young’s modulus increased compared to the pristine chitosan. The in vitro fungal colonization ofdiacid monomer, PAIs, pure CS and blend CS/PAI samples were performed using Aspergillus niger fungi. After biodegradation, the pure CS showed the highest weight loss of 21.2 wt % among the samples. The blend CS/PAI samples also showed higher weight losses compared to the pure PAIs.  

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Role of Nano-Sized TiO2 on Mechanical and Thermal Behavior of Starch/Poly (vinyl alcohol) Blend Films

A novel Starch/Poly (vinyl alcohol)/nano-Titanium dioxide (ST/PVA/nano-TiO2) biodegradable nanocomposite film was prepared by homogeneously dispersed TiO2 nanoparticles in different ratios of starch/PVA-based materials, via a solution casting method. Glycerol was used as plasticizer. The mechanical and thermal properties of films were studied using tensile and perforation strength tests and the...

full text

role of nano-sized tio2 on mechanical and thermal behavior of starch/poly (vinyl alcohol) blend films

a novel starch/poly (vinyl alcohol)/nano-titanium dioxide (st/pva/nano-tio2) biodegradable nanocomposite film was prepared by homogeneously dispersed tio2 nanoparticles in different ratios of starch/pva-based materials, via a solution casting method. glycerol was used as plasticizer. the mechanical and thermal properties of films were studied using tensile and perforation strength tests and the...

full text

Biodegradable kefiran-chitosan-nanocellulose blend film: Production and physical, barrier, mechanical, thermal, and structural properties

In this study, biodegradable kefiran-chitosan-nanocellulose blend films were developed and their physical, mechanical, barrier, thermal and structural properties determined. Results showed that adding nanocellulose had not any significant effect on the thickness, moisture content and water solubility. Also, water vapor permeability, tensile strength and lightness increased and the elongation at...

full text

Thermal Stability, Sorption Properties and Morphology of Films of Dipeptide and Tripeptide Based on L-Glycine

The effect of the number of amino acid residues in L-glycyl-L-glycine and L-glycyl-L-glycylL-glycine on thermal stability of powders, the sorption properties and surface morphology of thin films has been found. Dipeptide forms the film coated with disk-shaped nano-objects on the hydrophilic substrate, while tripeptide self-organizes to the film coated with nano-crystals on the hydrophobic subst...

full text

Influence of Phase Behavior and Miscibility on Mechanical, Thermal and Micro-Structure of Soluble Starch-Gelatin Thermoplastic Biodegradable Blend Films

Polymer blends of cold water soluble starches (amylose or amylopectin soluble starch) with gelatin were prepared using solvent casting method. The solid state miscibility and polymer-polymer interactions between the constituent polymers were studied by fourier transforms infrared spectroscopy (FTIR), X-ray diffraction (XRD), differential scanning calorirmetry (DSC), light optical microscopy (OP...

full text

Biodegradable Zein-Based Blend Films: Structural, Mechanical and Barrier Properties.

The effect of adding a hydrocolloid on the structural, mechanical and barrier properties of zein-based blend films is evaluated. Zein-oleic acid blend film with added xanthan gum (Z-OA-XG) showed higher water solubility (13.09%) and opacity (8.49 AU/mm) than zein-oleic acid (Z-OA) film (10.80% and 5.19 AU/mm, respectively). Furthermore, Z-OA film had greater flexibility with lower Young's Modul...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 36  issue 2

pages  55- 70

publication date 2017-05-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023